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標(biāo)題: Titlebook: Chemoselective Nucleophilic α-Amination of Amides; Miran Lemmerer Book 2020 The Editor(s) (if applicable) and The Author(s), under exclusi [打印本頁]

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書目名稱Chemoselective Nucleophilic α-Amination of Amides影響因子(影響力)




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書目名稱Chemoselective Nucleophilic α-Amination of Amides網(wǎng)絡(luò)公開度學(xué)科排名




書目名稱Chemoselective Nucleophilic α-Amination of Amides被引頻次




書目名稱Chemoselective Nucleophilic α-Amination of Amides被引頻次學(xué)科排名




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書目名稱Chemoselective Nucleophilic α-Amination of Amides讀者反饋




書目名稱Chemoselective Nucleophilic α-Amination of Amides讀者反饋學(xué)科排名





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作者: 獨(dú)白    時間: 2025-3-22 04:02
Book 2020 Lemmerer expands a novel chemoselective approach for the synthesis of these intriguing molecules together with Univ.-Prof. Dr. Nuno Maulide’s team...The Author:.Miran Lemmerer. is currently pursuing his PhD studies under supervision of Prof. Dr. Nuno Maulide at the Department of Organic Chemistry, University of Vienna, Austria.?.
作者: hallow    時間: 2025-3-22 05:23
Book 2020-amino amides, a subclass of α-amino carbonyls, in the presence of other carbonyls is usually challenging, due to the required harsh conditions. Miran Lemmerer expands a novel chemoselective approach for the synthesis of these intriguing molecules together with Univ.-Prof. Dr. Nuno Maulide’s team...
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Chemoselective Nucleophilic α-Amination of Amides978-3-658-30020-3Series ISSN 2625-3577 Series E-ISSN 2625-3615
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Limit Cycles and Structural Stability,tion aldehydes, ketones, esters, amides and nitriles form enolates which react with electrophiles to yield α-functionalized products. Examples of such electrophiles include aldehydes, ketones or esters themselves.
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978-3-658-30019-7The Editor(s) (if applicable) and The Author(s), under exclusive license to Springer Fachmedien Wies
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https://doi.org/10.1007/978-3-540-32902-2In this study, a novel concept for the α-functionalisation of amides was further developed. The Umpolung of amides enables a nucleophilic α-amination with several sulfonamide derivatives. This method reliably affords good yields and shows a high functional group tolerance. Additionally, α-oxygenation was achieved using similar conditions.
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Normal Forms and Elementary Singularities,All glassware was flame-dried before use and the reactions were performed under an atmosphere of argon. All dry solvents were bought from Acros and used as received. All other reagents, the synthesis of which is not described below, were used as received from commercial suppliers.
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Conclusion and Perspectives,In this study, a novel concept for the α-functionalisation of amides was further developed. The Umpolung of amides enables a nucleophilic α-amination with several sulfonamide derivatives. This method reliably affords good yields and shows a high functional group tolerance. Additionally, α-oxygenation was achieved using similar conditions.
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